Analytical Applications of Ion Exchangers by J. Inczédy and I. Buzás (Auth.)

By J. Inczédy and I. Buzás (Auth.)

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Amer. Chem. Soc, 1956, 7 8 , 249. 11. H. A. Sober and E. A. Peterson, / . Amer. Chem. Soc, 1954,76, 1711; 1956, 7 8 , 751. 12. J. D . Guthrie and A. L. Bullock, Ind. Eng. ,1960, 5 2 , 935; Analyt. , 1962, 9 , 1269. 13. G. Semenza, Helv. Chim. Acta, 1960, 4 3 , 1057. 14. N. V. Stamicarbon, Holl. Pat. 75705, 1954. 15. Directie van De Staatsmijnen in Limburg, Holl. Pat. 72245, 73798, 1953; 75968, 1954. 16. Ε. L. Holmes and L. E. Holmes (Permutit Co), EP 588380, 1947. 17. T, R. E. Kressman and J. A.

Ion-exchange resins are selective for ions. Multivalent ions are more strongly absorbed from dilute solutions than ions of lower valence. The order of absorption strengths on strongly acidic cation-ex­ change resins of ions with the same valence is nearly identical with the Hofmeister's lyotropic row: Li+ < H+ < Na+ < NH4+ < < Rb+ < Cs+ < Ag+ < T1+; Mn^+ < Mg2+ < Zn2+ < Co^^ < Cu^^ < Cd^^ < Ni^^ < Ca2+ < Sr2+ < Pb2+ < < Ba^^; Al^^ < Sc^^ < Y^-^ < Eu^-^ < Sm^+ < Nd^"^ < Pr^"' < Ce^+ < La^"'. In the case of ions carrying an identical charge, the absorption strength increases with decreasing diameter of the hydrated ion.

C. H. McBurney (Rohm and Haas Co), USP 2591573, 1932. 35. K. W. Pepper, H. M. Paisley and M. A. Young, / . Chem. Soc (London), 1953, 4097. 36. W. C. Bauman and R. McKellar (Dow Chem. ), USP 2614099, 1952. 37. Ion Exchange and its Application, Ed. Chmutov, Akad. Nauk USSR, Moscow, 1959. 38. Researches in the Fields of Ion-Exchange, Partition and Precipitation Chromatography, Akad. Nauk USSR, Moscow, 1959. 39. P. Biacs and G. Nemeshegyi, unpublished work. Technical Univ. Budapest, 1960. 40. J, I.

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